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GAUCHO BLE

Anthraquinone

CAS: 84-65-1

Molecular Formula: C14H8O2

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GAUCHO BLE - Names and Identifiers

Name Anthraquinone
Synonyms AQ
CORBIT
Hoelite
CORBIT(R)
GAUCHO BLE
ANTHRAQUINONE
Anthraquinone
Anthracenedione
9,10-Anthraquinone
anthra-9,10-quinone
9,10-Dioxoanthracene
anthracene-9,10-dione
Melting point standard Anthraquinone
CAS 84-65-1
EINECS 201-549-0
InChIKey RZVHIXYEVGDQDX-UHFFFAOYSA-N

GAUCHO BLE - Physico-chemical Properties

Molecular FormulaC14H8O2
Molar Mass208.21
Density1.438
Melting Point284-286 °C (lit.)
Boling Point379-381 °C (lit.)
Flash Point365°F
Water Solubility<0.1 g/100 mL at 23 ºC
SolubilitySoluble in hot benzene and hot toluene, insoluble in cold benzene, insoluble in water, slightly soluble in ethanol, ether and chloroform. Soluble in concentrated sulfuric acid.
Vapor Presure1 mm Hg ( 190 °C)
Vapor Density7.16 (vs air)
AppearanceDark yellow powder
ColorYellow-green to khaki to tan
Merck14,687
BRN390030
Storage Conditionno restrictions.
StabilityStable. Incompatible with strong oxidizing agents. Combustible.
SensitiveEasily absorbing moisture
Refractive Index1.5681 (estimate)
MDLMFCD00001188
Physical and Chemical PropertiesTrait: yellow needle-like crystal.
melting point 286 ℃
boiling point 376.8 ℃
relative density 1.438
flash point 185 ℃
solubility: soluble in ethanol, ether and acetone, insoluble in water.
UseUsed as dye intermediate, papermaking cooking agent and hydrogen peroxide raw materials

GAUCHO BLE - Risk and Safety

Hazard SymbolsXi - Irritant
Irritant
Risk CodesR43 - May cause sensitization by skin contact
R36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS36/37 - Wear suitable protective clothing and gloves.
S37/39 - Wear suitable gloves and eye/face protection
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S24 - Avoid contact with skin.
UN IDs3077
WGK Germany1
RTECSCB4725000
TSCAYes
HS Code2914 61 00
Hazard Class9
Packing GroupIII
ToxicityLD50 orally in Rabbit: > 5000 mg/kg

GAUCHO BLE - Upstream Downstream Industry

Raw MaterialsBenzene
Phthalic anhydride
Anthracene
Sulfuric acid
Aluminum chloride
Nicotinic acid
Downstream ProductsHydrogen peroxide
ethyl caproate

GAUCHO BLE - Reference

Reference
Show more
1. Li Min, Guo Yankai, Ma Zhiyuan, etc. Enhancement of electrolytic decolorization of acid red B catalyzed by quinone-modified electrode [J]. Journal of Hebei University of Science and Technology, 2014(03):291-295.
2. [IF = 1.986] Yixin Leng et al."Differentiation of isomers of oxygenated polycyclic aromatic hydrocarbons by laser desorption laser post-ionization time-of-flight mass physicl." Int J Mass Spectrom. 2021 Sep;467:116618

GAUCHO BLE - Nature

Open Data Verified Data

needle-like crystals or powders. Insoluble in water, ethanol and chloroform, soluble in concentrated sulfuric acid, more soluble in hot benzene, toluene nitrobenzene and aniline.

Last Update:2024-01-02 23:10:35

GAUCHO BLE - Preparation method

Open Data Verified Data

Refined anthracene oxidation method

1. The gas-phase fixed bed oxidation method adds refined anthracene to the vaporization chamber for heating and vaporization, and mixes it with air in a ratio of 1: (50-100). The mixed gas enters the oxidation chamber and undergoes oxidation at (389 ± 2) ℃ under the catalysis of V2O5. After thin-walled condensation, the product is obtained.

2. The liquid phase oxidation method measures the refined anthracene and adds it to the reaction vessel, followed by the addition of trichlorobenzene, which is dissolved under stirring. Then add nitric acid dropwise, control the reaction temperature to 105-110 ℃, remove the by-product NO, and react for 6-8 hours. After that, reduce the pressure and evaporate the solvent, cool and crystallize to obtain the product.

Phthalic anhydride method

Measure the phthalic anhydride and add it to the reaction vessel. Heat and dissolve it with benzene while stirring. Heat to 370-470 ℃ and allow the mixed gas to undergo gas-phase condensation through a silicon aluminum catalyst to obtain the product.

Carboxyl synthesis method

Add the measured amount of benzene to the reaction vessel, pass CO at 4.88 MPa, and react at 200 ℃ for 4 hours until the CO pressure no longer decreases, and the reaction is complete. Processed products.

Last Update:2023-12-08 10:00:33

GAUCHO BLE - Safety

Open Data Verified Data
  • This product has low toxicity. Can cause allergic eczema, rhinitis, bronchial asthma. The production workshop should be well ventilated, the equipment should be sealed, and the operator should wear protective equipment.
  • packed in an iron drum or in a hemp bag, lined with a plastic bag. The net weight of each barrel (bag) is 100 ~ 200kg. Keep dry, fire-proof and moisture-proof during storage. According to the general provisions of the storage and transportation of toxic chemicals.
Last Update:2022-01-01 10:42:53
GAUCHO BLE
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Shanghai Macklin Biochemical Co., Ltd
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Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
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Shanghai Macklin Biochemical Co., Ltd
Featured ProductsSpot supply
Product Name: Anthraquinone Visit Supplier Webpage Request for quotation
CAS: 84-65-1
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328 Click to send a QQ message
WhatsApp: +86-18821248368
Jiangsu Pules Biotechnology Co.,Ltd.
Featured ProductsSpot supply
Product Name: Anthraquinone Request for quotation
CAS: 84-65-1
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
JIANGSU BSECHEM CHEMICAL TECHNOLOGY CO., LTD.
Spot supply
Product Name: Anthraquinone Request for quotation
CAS: 84-65-1
Tel: +86-17505207175
Email: r@reformchem.com
Mobile: +86-17505207175
QQ: 3787852685 Click to send a QQ messageSend QQ message
Wechat: chemical6666
Nantong Reform Petro-Chemical CO., LTD.
Spot supply
Product Name: Anthraquinone Request for quotation
CAS: 84-65-1
Tel: +86-17551318830
Email: r@reformchem.com­
Mobile: +86-17551318830
QQ: 3785839865 Click to send a QQ messageSend QQ message
Wechat: chemical6666 
Hubei Longxin Chemical Industry Co., Ltd
Spot supply
Product Name: Anthraquinone Request for quotation
CAS: 84-65-1
Tel: 15335994747
Email: 3521670276@qq.com
Mobile: 15335994747
QQ: 3521670276 Click to send a QQ message
MedChemExpress (MCE)
Multiple SpecificationsSpot supply
Product Name: Anthraquinone (Standard) Visit Supplier Webpage Request for quotation
CAS: 84-65-1
Tel: 609-228-6898
Email: sales@medchemexpress.com
     tech@medchemexpress.com
Mobile: 609-228-6898
SKYRUN INDUSTRIAL CO.,LTD
Spot supply
Product Name: 910-Anthraquinone Visit Supplier Webpage Request for quotation
CAS: 84-65-1
Tel: +86 0571-86722205
Email: sales@chinaskyrun.com
Mobile: +8618958170122
QQ: 2531159185 Click to send a QQ messageSend QQ message
Wechat: chinaskyrun
SHANGHAI ACMEC BIOCHEMICAL TECHNOLOGY CO., LTD.
Spot supply
Product Name: Anthraquinone Visit Supplier Webpage Request for quotation
CAS: 84-65-1
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922 Click to send a QQ message
Wechat: 18621343501
WhatsApp: +86-18621343501
Hefei TNJ Chemical Industry Co.,Ltd.
Product Name: Anthraquinone Request for quotation
CAS: 84-65-1
Tel: 0086-551-65418684
Email: sales@tnjchem.com
     info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840 Click to send a QQ message
Wechat: 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
Shanghai Yuanye Bio-Technology Co., Ltd.
Multiple SpecificationsSpot supply
Product Name: Anthraquinone Visit Supplier Webpage Request for quotation
CAS: 84-65-1
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409 Click to send a QQ message
View History
GAUCHO BLE
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Raw Materials for GAUCHO BLE
Benzene
Phthalic anhydride
Anthracene
Sulfuric acid
Aluminum chloride
Nicotinic acid
Downstream Products for GAUCHO BLE
Hydrogen peroxide
ethyl caproate
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